The multifunctional features of pressure sensitivity and energy-absorption capability of flexible electromechanical sensors are desirable for practical applications, such as personal protection, crash mitigation, and protective packaging of sensitive elements. However, there are still challenges in developing ultrasensitive pressure sensors with high energy absorption capability. Herein, a bio-inspired flexible piezoresistive MWCNTs/PDMS composite with a multilayered architecture mimicking the ant tentacle and the pomelo peel is innovatively constructed, which can simultaneously detect physical stimuli in an extensive pressure range and absorb impact energy. The composite architecture is  composed of the bottom-layer interlocked tentacle-like conical micropillars and the top-layer pomelo peel-inspired hierarchically enclosed-porous microstructure, which has successfully wrapped air inside to form a solid-gas dual phase structure with enhanced energy absorbing capability and piezoresistivity. The composite architecture was manufactured by a laser-engraving method associated with the controlled solidification process of the composite by regulating the vacuum pumping rate in the pre-curing condition. Owing to the hollow-shaped tentacle-like conical micropillars, the contact area can be dramatically increased within a subtle pressure loading, leading to superb pressure sensitivity of ~26.1 kPa
1. Simultaneously, the hierarchically enclosed-porous structure with trapped air (gas-phase), acting as an air cushion packaging, imitating the pomelo peel provides the composite architecture with exceptional mechanical energy absorption of ~2.74 MJ/m3 and an extensive pressure sensing range from 0.1 Pa to 60 kPa. As a result, the as-proposed composite sensor was able to detect mechanical signals such human finger tapping, wrist flexion, and pendulum hammer impact. Numerical simulations also showed that the wrapped air inside the hierarchical enclosed-porous structure improved the mechanical damping properties of the composite architecture. It is envisioned that our finding could contribute to the development of multifunctional materials to meet the growing demands for next-generation electronic systems, inspired by sophisticated architectures from nature.